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It was from "Gotta Catch You Later". It was part of 4Kids' montage salute/song to Misty -- their playing on the Ash/Misty relationship and her departure. That's the only time that scene from the "Ready Go" OP makes it to the dub.
Edit: And as far as I know, never been used in any of the Japanese episodes.
Awww... gotta catch ya later.. it was such a sad episode!! That was the last time we ever saw Misty travelling with Ash on long journeys.. she does still appear in a few episodes later, but no more long journeys for her.. :(
It was from "Gotta Catch You Later". It was part of 4Kids' montage salute/song to Misty -- their playing on the Ash/Misty relationship and her departure. That's the only time that scene from the "Ready Go" OP makes it to the dub.
Edit: And as far as I know, never been used in any of the Japanese episodes.
Yes, this scene does not come from the original animation. 4Kids changed the entire montage in that episode to be a parting of Satoshi and his friends to a Satoshi/Kasumi thing.